Project Summary

Jurassic formations in the Queensland portion of the Surat Basin were used as a case study, representing prospective low‑salinity, siliciclastic geological CO2 storage reservoir systems. Geochemical investigations showed that the principle reaction pathways in low-salinity aquifers are the same as in high-salinity aquifers.

However, since more acid is formed in low-salinity water and the acid buffer capacity is low in formation water of the Surat Basin, Queensland, the formation water becomes relatively acidic, leading to a typical pH of 4. The prospective reservoir in the Surat Basin is the Precipice Sandstone, a very homogenous rock unit, largely dominated by quartz. As this mineral is hardly reactive under CO2 storage conditions, the geochemical reactivity of this unit overall is very low. Consequently, the long-term CO2 trapping capacity in the form of carbonate mineral precipitation is very low as well.

Detailed mineral analysis of units above the Precipice Sandstone revealed the Boxvale Sandstone Member may be suitable for above-reservoir monitoring purposes.

Relatively high porosity, permeability and a thickness of several meters are characteristic for the Boxvale Sandstone Member, making it a good secondary containment formation with the Evergreen Formation sealing strata above. This rock unit is also distinct in its mineral composition as it contains a large proportion of feldspar, a mineral known to dissolve relatively quickly in CO2– enriched water. This would lead to rapid changes in the water composition and could serve as an indication of CO2 leakage from the primary storage reservoir (Precipice Sandstone).

In addition, the compilation of stress field data led to a much higher data density in the Surat Basin than anything previously published and thereby reduced the uncertainty in predicting the rock mechanical response to CO2 injection and storage. Preliminary rock mechanical considerations suggest faults with strikes that are approximately at 30 degrees to the maximum horizontal stress direction will be at greatest risk of reactivating due to the fact they have the highest shear to normal stress on the fault plane.

Available Reports

Geomechanical impacts and monitoring of CO2 storage in low salinity aquifers

This report addressed the following objectives:

  • Characterisation of the lithology and lithostratigraphy primarily of the Lower Jurassic section of the Surat Basin, Queensland, with an emphasis on the characterisation of the Precipice Sandstone as CO2 storage reservoir and the above-lying Evergreen Formation as the regional seal.
  • Extending the horizontal and vertical stress field data base for the Surat Basin to better constrain the regional pattern of in-situ stress orientation. This can provide relevant data for future rock mechanical analysis as part of the seal capacity characterisation from the primary storage reservoir into the above-lying rock unit.
  • Simulate the geochemical impact of CO2 impurities such as SO2 at reservoir scale.
  • Characterise long-term CO2-water-rock reactions in low-salinity aquifers and identify characteristic changes in water composition that could be used as leakage indicators if stored CO2 were to migrate from the primary storage reservoir into an above-lying rock unit.

 

Project Name:
Geochemical impacts and monitoring of CO2 storage in low salinity aquifers

Research Organisation:
CO2CRC

Status:
Completed, 2016

Authors:
R Haese, A Frank, M Grigorescu, K Horner, DKirste, U Schacht, E Tenthorey

Reference:
7-1110-0088

Research Program: Carbon Transport + Storage
Demonstration: Surat Basin
Research Focus: Injectivity, Geochemistry

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